Anping
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Posts: 533
What I collect: Hong Kong, Aden & States & odd stuff I like.
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Post by Anping on Aug 31, 2017 1:12:44 GMT
The Chloromine-T, marketed as Halamid by Pharmaq, is the cheaper chemical. Foxit is supplied in a tiny 5 (or perhaps 10 gram) bag and now costs £4.75. I can't recall exactly how much I paid at the time for the Halamid product, but it was around £15 for 100 grams.
Note that although the container shows an expiry date, it can largely be ignored if stored with the cap on in a cool place. Mine is just over 4 years out of date yet still appears to be doing its stuff (perhaps its strength has been very slightly diminished over time but impossible to measure).
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Post by smauggie on Aug 31, 2017 1:50:11 GMT
Oh, thanks for clarifying.
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Beryllium Guy
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What I collect: Worldwide Stamps 1840-1930
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Post by Beryllium Guy on Sept 17, 2020 21:22:18 GMT
Thanks to some PM correspondence from tobben63, I was reminded about these two old threads today, so I decided to merge them and give them a bump. I encourage those who have not seen these threads before to start from the beginning and have a read-through. I am always looking for ways to improve my stamps, whether it is simple cleaning by soaking in water, or treatment with other chemicals, some of which are mentioned in this thread. One of the keys to successful treatment is correctly identifying the problem in the first place. Foxing is a type of mold, and has particular treatments that can largely remove it, as you will see in reading this thread. Departed member Clive ( Anping) seems to have been particularly successful with his method for treating foxing. Since moving to the UK, I have bought a packet of the Chloromine-T that he recommended. I will try it at some point and report my results. I am setting aside some items both for testing the process, and then an actual salvage attempt. But please remember that all staining is not necessarily the same thing. Brown stains can result from other problems besides mold, and just because a treatment works on one type of stain does not mean that it will work on another. So, use caution, and whenever possible, first test your process on a stamp that you can afford to lose before risking one that you really care about! Good luck with your attempts, and if they deal with foxing, please post your before-and-after results here. We can all use a good success story!
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Londonbus1
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Cinderella Stamp Club Member 3059
Posts: 5,064
What I collect: Wonderland; 1912 Jubilee International Stamp Exhibition, London ('Ideal' Stamp, ephemera); French Cinderellas with an emphasis on Poster Stamps; Israel and Palestine Cinderellas ; Jewish National Fund Stamps, Labels and Tags; London 2010, A Festival of Stamps (anything); South Africa 1937 Coronation issue of KGVI, singles or bi-lingual pairs.
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Post by Londonbus1 on Sept 17, 2020 21:46:32 GMT
I was given a demonstration by a fellow collector who came to exchange stamps earlier in the summer.
This is what we used and it worked superbly, no after effects (he showed me items he did a year ago).
1. a few drops of Kalium Permanganate in water. 2. Soak stamp for 30 seconds, the stamp will go an 'icky' brown. 3. Take out with tongs (old ones) and put into Lemon juice. When stamp is clean... 4. Put in fresh water to rinse. 5. Dry a little and press.
Perfect every time.
Londonbus1.
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Beryllium Guy
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What I collect: Worldwide Stamps 1840-1930
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Post by Beryllium Guy on Sept 17, 2020 21:55:58 GMT
Great stuff, LB1 ( Londonbus1 ), I had never heard about this before! By the way, for anyone confused about the term "kalium permanganate", it is also known as "potassium permanganate" (chemical formula KMnO 4), which may sound more familiar to some. Also, what type of KMnO 4 do you use? You mention drops, but what is the concentration of the liquid? When I look for sources from which to buy, most of what I see online are solid forms, such as crystals. Any further comment about this aspect? I love it when bumping an old thread after years of dormancy gets a great post as a reward.... thanks, Michael!
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Londonbus1
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Cinderella Stamp Club Member 3059
Posts: 5,064
What I collect: Wonderland; 1912 Jubilee International Stamp Exhibition, London ('Ideal' Stamp, ephemera); French Cinderellas with an emphasis on Poster Stamps; Israel and Palestine Cinderellas ; Jewish National Fund Stamps, Labels and Tags; London 2010, A Festival of Stamps (anything); South Africa 1937 Coronation issue of KGVI, singles or bi-lingual pairs.
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Post by Londonbus1 on Sept 18, 2020 6:39:35 GMT
I'll contact my friend in Tel Aviv after cooking and cleaning. Will get more details if any are to be had. I believe the little bottle had a dripper attached to the cap and we used 6 or 7 drops. I will get exact details later. Londonbus1
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Beryllium Guy
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Post by Beryllium Guy on Nov 9, 2020 9:28:15 GMT
Moderator Note: This post and the one immediately following were moved over from a thread titled Samuel Jones & Co. started by daniel
Wow, daniel , that's some notebook! Thanks for sharing. I admit to having little knowledge about stamp paper or gum arabic, so this is quite educational for me. Just a quick question about the stamps: are they all stuck down in the notebook, then? If indeed they are, as it appears, I am surprised that there doesn't seem to be any evidence of staining or toning due to the long-term contact with ordinary (i.e. not acid-free) paper. The vast majority of stamps that I have acquired that have been mounted on ordinary notebook paper exhibit brown staining, especially around the edges. I have always imagined that it is a reaction between the gum and the acid in the paper. But perhaps that may have something to do with it. Most of the material I have acquired was mounted using hinges, rather than just having the gum used to stick the whole thing down to the notebook paper. It makes me wonder if most of the problems with staining were avoided when your stamps were presumably licked and then fully stuck down to the sheets. OK, sorry for the digression! Bottom line: these are some beautiful Cinderella stamps, and I am really enjoying this new thread!
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cursus
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What I collect: Catalan Cinderellas. Used Switzerland, UK, Scandinavia, Germany & Austria. Postal History of Barcelona & Estonia. Catalonia pictorial postmarks.
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Post by cursus on Nov 9, 2020 10:11:56 GMT
As far as I know, "staining" of stamps/cinderellas is dur to mold feeding and growing on gum. Thus, a biological, not a chemical process. Due to this, the treatment with a disinfectant (like Sodium Hypochloride) solves the problem, as well as bleaching the stains. But, being a food-microbiologist by training, I could be somewhat biased...
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Beryllium Guy
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Post by Beryllium Guy on Nov 9, 2020 10:46:31 GMT
Thanks for your response, Joan ( cursus )! I have decided to move my post and your response over to this thread about staining and foxing, so that Daniel's ( daniel ) content will not be steered off course. I should have known better than to post off-topic remarks into the thread.... sorry, everyone! OK, well, to the topic of staining on stamps. Joan, I completely agree that foxing is due to mold, which is indeed a biological process. But mold is not the only possible source of staining, and some of the other sources are chemical rather than biological. If you look at the very first post in this thread made by madbaker , the brownish-black staining on his stamps appears to have been caused by a reaction with adhesive tape. So far, I believe that I have seen stains on stamps resulting from a variety of sources: - Mold (mould) also known as foxing
- Residue or reaction from adhesive tape
- Reaction with non-acid-free paper
- Fugitive ink from adherent paper, generally liberated during soaking
- Ink due to writing on the stamp (can also be liberated during soaking)
- Residue of ink due to chemical processes to remove ink or postmarks
- Residue or reaction from adhesive in certain kinds of old stamp hinges
- Residue from rusting of iron, as when in contact with a paper clip, for example
- Residue from rubber bands that have melted in contact with the stamps, often seen on bundled groups of covers
Wow, that list ended up being a lot longer than I thought it would be when I started this post. Nonetheless, I feel sure that there must be other sources of staining, too. I have examples of most of these in my accumulations, so I will try to take some scans and post some images. Again, I completely agree that foxing is due to mold, and it may well be the most common source of staining, but in my experience, it is not the only source. Frankly, that is one of the real issues for collectors who want to do something about staining or color changes in a stamp. It is very important to identify correctly the source of the staining, as the possible solutions will be different, depending on whether it is due to a mold or a chemical reaction. More opinions are welcome, of course!
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Londonbus1
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Cinderella Stamp Club Member 3059
Posts: 5,064
What I collect: Wonderland; 1912 Jubilee International Stamp Exhibition, London ('Ideal' Stamp, ephemera); French Cinderellas with an emphasis on Poster Stamps; Israel and Palestine Cinderellas ; Jewish National Fund Stamps, Labels and Tags; London 2010, A Festival of Stamps (anything); South Africa 1937 Coronation issue of KGVI, singles or bi-lingual pairs.
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Post by Londonbus1 on Mar 9, 2021 14:37:32 GMT
Further to my post in September 2020 and at the request of others, here is the full 'recipe' for cleaning toned, stained or dirty stamps. This method came to me by a fellow collector here in Israel. His friend, a Book restorer in Jerusalem, gave him the same demonstration he gave to me in my home last June. The method has been a proven success for paper and card items. Work outside or in a workshop/workroom if possible. Extra care should be taken if working in your Kitchen/Bathroom (Only because of staining). 1). Prepare 3 dishes. Plastic containers are fine. Fill one with lukewarm water, one with sieved lemon juice with 10% water added and the third with cool water. The amounts needed depend upon how many stamps one is cleaning. 2). Put 3 small scoops of Kalium Permanganate crystals (see image above) into the lukewarm water and stir with old spoon or other utensil. The bottom of the container should not be visible. 3).Make sure any hinges or other gunk are removed from the stamp beforehand. Stamps that have been coloured by envelopes (Red/Yellow/Orange etc) should not be included. No more than 30 stamps at a time, because timing is important. 4). Place stamps in KP mix and press down so completely covered. Leave for 5 minutes. 5). Take out stamps with old tweezers/tongs, they will be a horrid 'icky' brown colour. They will look awful !! Place into the lemon juice mix for 3 minutes. 6). You can view them slowly becoming clean.After 3 minutes put into the clean water. 7). 2 or 3 minutes and they should be ready for drying in the way you are used to, shaking off the excess water or using a paper towel first before pressing. OTHER TIPS. Use a plastic sheet on the work surface if working in the kitchen or other area of importance to avoid staining. Wear an apron. Wear plastic gloves. On really heavily toned stamps with marks in the centre of the stamp, it might not work 100% but equally, it might. A second attempt can be made. Work carefully and with patience. If you have just had a row with your other half, do not attempt this until you have kissed and made up !! RESULTS. It works. I have stamps here that look great, even with handstamped overprints but I cannot guarantee that all overprints will be OK because of the different types of substances used. It can be an experimental work for overprint types. It has been tested in Jerusalem for long-term results and they are excellent. I don't have details but I did see stamps that have been cleaned years before with no return of foxing. I tried it on one cancelled stamp and the cancel did fade very slightly but I am told that is not always the case. Again it depends, most likely, on how and with what, they are cancelled. Some of the items I posted in the 'Jewish National Fund' topic (Cinderella Category) were cleaned in this way. Some were very badly toned. So there it is. From an expert in Book Restoring in Jerusalem to an International Stamp Forum online. Have fun, good luck and above all else.....Happy Collecting ! Londonbus1.....
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kasvik
Member
Posts: 607
What I collect: Cancels mostly, especially Sweden Gävle and Lidingö, Switzerland Geneva, Germany Pforzheim
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Post by kasvik on Sept 13, 2021 23:20:51 GMT
Anybody have a thought what is happening to this cover? The disappearing blue under some of the hand writing? I like the cover--nice cancels, good starting place and destination--but haven't bought. Before I plunk, tell me it is not infectious.
- Not foxing, maybe staining?
- What is the red 6? Not postage due; the letter was PD.
- And a smudged cancel behind, just to drive me bananas.
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WERT
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Post by WERT on Sept 13, 2021 23:55:11 GMT
kasvik..Interesting cover.
Robert
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vikingeck
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Post by vikingeck on Sept 14, 2021 11:16:16 GMT
kasvik..Interesting cover.
Thanks Robert
What do you mean Robert? Is this one of those arguments of chicken and egg, where you try to guess which black mark is on top? do you think the ink is on top of the cancel ………? If that is what you are implying it surely is wrong, the address must be first. I have argued for years that for black on black, it is virtually impossible for the amateur to separate and say which came first . Often software such as Retroreveal etc is inconclusive and simply confuses! as to kasvik ‘s question there must be some chemical component in the ink which has reacted unfavourably with the paper. I do not know the cause but I have seen very similar effects on quite a number of letters and covers from the mid 19th century. The smudged postmark Aaron is K.WURTT.FAHREND POSTAMPT In 1866 Wurttemberg is a separate kingdom, Germany as such does not exist as a unified country until 1872. The UPU had not yet been formed so the individual countries had treaties with each other . The Swiss stamp and PD means it has been paid and the red 6 will indicate the proportion of the cost (out of the 40 centimes stamp) due to one of the countries , I suspect Wurttemberg , for delivery in Stuttgart. i don’t recall the currency used but possibly 6 Kreuzer? They would claim from Switzerland.
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vikingeck
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Post by vikingeck on Sept 14, 2021 12:51:54 GMT
K.WURTT FAHREND POSTAMPT I translate as Royal ( Konglich) Wurttemberg Traveling Post office Probably on a train ?
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WERT
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Post by WERT on Sept 14, 2021 13:50:12 GMT
Hi vikingeck
I did not go further than just looking at the cover...You are correct, signature first Cancel after. I did use my software program which DOES isolate markings for collectors...It removes colours and just leaves out lines.
I have used the program for big collectors to isolate forgeries before getting a stamp certified. Below is the signature first cancel after...
Robert
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vikingeck
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What I collect: Samoa, Tobacco theme, Mail in Wartime, anything odd and unusual!
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Post by vikingeck on Sept 14, 2021 13:59:39 GMT
I have to say that GWIDDION scan is impressive! Far better than retroveal. It does seem to work on different layers .
GWYDDION sounds Welsh ? but I see it is Czech!
I tried downloading but my security blocked it as not secure and " unsafe" .
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WERT
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Post by WERT on Sept 14, 2021 14:10:27 GMT
Thanks vikingeck GWYDDION is FREE to download...I use so many more FREE software programs. BNAPS is using a lot of my software programs to enhance stamp collecting for collectors on their study group called "Digital Philately"
Robert
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Beryllium Guy
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What I collect: Worldwide Stamps 1840-1930
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Post by Beryllium Guy on Sept 14, 2021 15:58:27 GMT
Anybody have a thought what is happening to this cover? The disappearing blue under some of the hand writing? I like the cover--nice cancels, good starting place and destination--but haven't bought. Before I plunk, tell me it is not infectious.
- Not foxing, maybe staining?
- What is the red 6? Not postage due; the letter was PD.
- And a smudged cancel behind, just to drive me bananas.
Aaron, as usual, a very interesting item from you, thanks for this! Lots of great discussion and contributions from Robert ( WERT) and Alex ( vikingeck).... really enjoying that. Coming back to your original question, the item does not look like it is foxed or moldy to me. I also don't think it is stained. Personally, I think that the reason that some of the blue paper is no longer blue under certain handwritten parts is because someone has made a correction. As an insufferable perfectionist myself, I can attest that if the blue striped paper is surface colored, then if someone tried to use an abrasive eraser to make a correction, they would have removed that surface design in the process. I also note that the ink seems darker or heavier in those places where the background is gone, which also would suggest that it could have been a correction, because people often write more heavily when trying to cover up an unwanted mistake. I have no special expertise in this area, but this is how it looks to me. If it has foxing, I think it would also be present on other parts of the cover, and there is no evidence of that. Just my opinion. Hope this may help a little with your decision to "plunk" or not!
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vikingeck
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Post by vikingeck on Sept 14, 2021 16:35:35 GMT
I agree the discolouration is NOT foxing. I also do not think the surface has been abraded. That would involve the Surname, the "Hof" and the whole of "Stuttgart", surely too much for a mistake needing corrected ?
I think it is more like bleaching of the underlying paper due to a corrosive substance in the ink itself. The darker heavier writing for Stuttgart etc suggests the writer dipped his pen again and used a fresh more generous flow of ink. As I have said already, I have seen similar discolouration on old letters in the past
Traditional black ink was made from Oak galls (tannic acid), Vinegar (acetic acid) and Ferrous sulphate.
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Beryllium Guy
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Post by Beryllium Guy on Sept 14, 2021 19:23:33 GMT
Many thanks for your reply, Alex ( vikingeck ). If there is anything I have learned in life and in philately, it is when to bow to superior knowledge, and I happily do so now! At the very least, we agree that there is no evidence of foxing. If the discoloured areas then, are due to a chemical reaction between ink and paper, rather than any sort of erasure or abrasion, is it logical then to link the writing of heavier ink to the reaction itself? I would then further suppose that the only reason that the same reaction did not occur in all inked areas was simply a matter of how much ink was applied? The budding alchemist in me is trying to work this out, because otherwise, I would have thought that there would have been discolouration underneath all of the written areas. That said, if what we can see on the cover is due to a reaction with the ink, then it does indeed seem to correlate with the amount of ink applied, as the areas of lesser application do not show the reaction. Really interesting discussion, Alex, thank you!
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WERT
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Post by WERT on Sept 14, 2021 20:05:06 GMT
To me it just looks like smearing of the address by the mailer's fingers while it was still wet...Just my opinion. Robert
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kasvik
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What I collect: Cancels mostly, especially Sweden Gävle and Lidingö, Switzerland Geneva, Germany Pforzheim
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Post by kasvik on Sept 15, 2021 0:37:10 GMT
It’s a treat to see so much insight. Thanks Chris @Beryllium_Guy Alex @vikingeck and Robert @wert
That’s much more than I hoped for. Robert, GWIDDION detection of layering is amazing. A free download? I’d take it even if it came with NotPetya.
Alex, you got my full attention with your description of ink elements and their role staining the envelope. And you made sense of K.Wurtt. Fahrend Postamt.
Now that you made it possible for me to read it, here is what I see: The letter left Geneva on 18 August 1866, where the sender paid 40 centimes for delivery in southern Germany. The 6 Kreuzer deduction was charged in red crayon after leaving Basel, to indicate refunding due to Baden, whose territory the letter crossed by train before being transferred at Karlsruhe. The back-side way-stamp, K.Wurtt.Fahrend Postampt [Royal Wurttemberg Mobile Post Office] applied on the next train, from Karlsruhe in Baden, to Stuttgart, the Wurttemberg capital. Upon arrival in Stuttgart, the letter received an arrival thimble stamp with the date 20 August 1866. At the same time a cute-looking 3 Kreuzer carrying fee was marked, to be deducted for final delivery to the Hotel Bayerischer Hof.
Well, it's plausible. I’m gonna buy it and write it up as best I can.
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vikingeck
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What I collect: Samoa, Tobacco theme, Mail in Wartime, anything odd and unusual!
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Post by vikingeck on Sept 15, 2021 13:02:31 GMT
Not the most powerful example of iron gall ink corrosion ! Snipped from Mowbray's 20/9/201 sale catalogue 39 lot 255 New Zealand , I have been looking for others which I know exist ( I had several examples in my early Denmark Collection but that was sold 10 years ago) you will see some of the interior writing causing white bleached areas , both right and left of the address ,just like those on the Swiss cover from kasvik
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Beryllium Guy
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Post by Beryllium Guy on Sept 15, 2021 14:23:02 GMT
Alex ( vikingeck), thank you very much for naming this phenomenon as "iron gall ink corrosion".... very helpful. Question: I did a web search using that specific terminology, and I found examples of documents where the ink had actually eaten all the way through the paper, not just bleached it a bit. When does the corrosion process stabilize, do you know? Should Aaron ( kasvik) be concerned that the corrosion might continue and eventually destroy his cover?
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banknoteguy
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What I collect: 19th Century US, High denomination US (> $1), 19th century covers US, Indian Feudatory States and most recently I acquired a BigBlue [with about 5,000 stamps] and pristine pages.
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Post by banknoteguy on Sept 15, 2021 14:55:07 GMT
I am not sure anyone knows when (or if) the corrosion process terminates. This is also a problem for archivists as iron gall ink was used for hundreds of years. Not all iron gall inks are the same. And not all of them produce this bleaching effect or worse -- destroying the paper completely. In my very limited understanding, it has to do more with the kinds of ferrous sulfates in the ink, more than how acidic the ink was/is.
I have a number of very old documents written in iron gall ink that show no such deterioration.
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kasvik
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What I collect: Cancels mostly, especially Sweden Gävle and Lidingö, Switzerland Geneva, Germany Pforzheim
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Post by kasvik on Sept 15, 2021 15:02:43 GMT
Not the most powerful example of iron gall ink corrosion !
Snipped from Mowbray's 20/9/201 sale catalogue 39 lot 255 New Zealand , I have been looking for others which I know exist ( I had several examples in my early Denmark Collection but that was sold 10 years ago)
you will see some of the interior writing causing white bleached areas , both right and left of the address ,just like those on the Swiss cover from kasvik Alex vikingeck and banknoteguy , you do me a serious service. Previously I though acidification of paper was preservation enemy number one. Apparently antiquarians have devoted considerable attention to the iron gall ink problem, too:
Iron Gall Ink Website, irongallink.org/ Iron gall ink on paper: Saving the words that eat themselves, British Library, very practical.
Sadly, no antidote one can readily apply to a nice old letter. But I agree, the stuff will last long enough for my puposes.
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brightonpete
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Post by brightonpete on Sept 15, 2021 15:04:47 GMT
Scan it before it disintegrates. Hopefully it won't though...
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vikingeck
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Post by vikingeck on Sept 15, 2021 15:10:22 GMT
Alex ( vikingeck ), thank you very much for naming this phenomenon as "iron gall ink corrosion".... very helpful. Question: I did a web search using that specific terminology, and I found examples of documents where the ink had actually eaten all the way through the paper, not just bleached it a bit. When does the corrosion process stabilize, do you know? Should Aaron ( kasvik ) be concerned that the corrosion might continue and eventually destroy his cover? The short answer is I have no idea! Google and Wikipedia are my friends! These inks all vary in composition , many were home made concoctions, so no uniformity. Thousands of contemporary covers exist showing no obvious harm or bleaching. It is a problem for Archivists, but as Aaron's cover has lasted 150years I suspect it may outlast all of us!
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tomiseksj
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What I collect: Worldwide stamps/covers, Cinderellas, Ohio Prepaid Sales Tax Receipts, U.S. WWII Ration ephemera
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Post by tomiseksj on Sept 15, 2021 15:13:40 GMT
I think the person best qualified to answer the question may be our very own eugene .
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Beryllium Guy
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Post by Beryllium Guy on Sept 15, 2021 16:53:01 GMT
Thanks for the further replies, Alex ( vikingeck) and banknoteguy. Steve ( tomiseksj), excellent point, I had momentarily forgotten about our new chemistry expert, eugene.... Perhaps he will favor us with a comment!
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